Abstract
Treatment of [Ru(η 5 -C 5 H 5 )(η 4 -C 5 H 4 O)] 2 (PF 6 ) 2 (1) with PR 3 (R=Me, Cy, Ph) and AsMe 3 results in the formation of 1,1'-disubstituted ruthenocenes of types [Ru(η 5 -C 4 H 4 PR 3 )(η 5 -C 5 H 4 OH)]PF 6 and [Ru(η 4 -C 5 H 4 -OH)]PF 6 , respectively, in 50-60% yield
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