Abstract

Etude des reactions de K + [(η 5 -C 5 Me 5 )Fe (CO) 2 ] − avec 2 electrophiles phosphores. Celle avec (i-C 3 H 7 ) 2 NPCl 2 donne (η 5 -C 5 Me 5 ) Fe(CO) 2 (PClN(i-C 3 H 7 ) 2 ). Ce compose reagit avec Ph 3 C + PF 6 − et AlCl 3 en formant un complexe phosphinidene L n M=PR

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