Abstract

Background: A one-pot method for the preparation of the corresponding alkoxy acetic acids by low-temperature ozonolysis of allyl ethers/esters followed by treatment with semicarbazide hydrochloride has been suggested. The reaction occurs via formation of acetoxyhydroperoxide, subsequent reduction of which depends on the process temperature and the nature of the starting substrate. Keywords: Allyl esters, olefins, semicarbazide hydrochloride, low-temperature ozonolysis, acetoxyhydroperoxide, intermediate, alkoxy acetic acids.

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