Abstract
The vinyl amine CF 2CF 2OCF 2CF 2N CFCF 2 and the tertiary amines CF 2CF 2OCF 2CF 2N CFXCF 2X (XCl, Br, OSO 2F) and CF 2CF 2OCF 2CF 2N CF 2Br have been reacted with ClOSO 2F to give a number of interesting fluorosulfate- containing products. The reactivity of bromine (chlorine) α and β to the nitrogen in these amines is compared. The structure of the products has been confirmed by 19F NMR, infrared and mass spectral studies, and by elemental analyses.
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