Abstract
A selected-ion drift chamber mass spectrometer has been used to determine the rate coefficients and product ions for the reactions of O 2 +, O 4 + and O 2 +·H 2O ions with simple inorganic and organic molecules in the gas phase at room temperature. Comparisons are made with FA and SIFT measurements. The observed reactions exhibit a wide variety of different routes including charge transfer, dissociative charge transfer, adduct formation and switching. Reaction efficiencies are discussed by comparison with rate coefficients calculated from Langevin or ADO Collision theory. The results of reaction with some chlorofluoromethanes are also included because of their importance in the stratosphere.
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More From: International Journal of Mass Spectrometry and Ion Processes
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