Reactions of monoazadienes with metal carbonyl complexes. XII. Reactions of the linear tetranuclear ruthenium complex Ru4(CO)10(CH3C:C(H)C(H):N-iso-Pr)2 with oxidizing reagents. Syntheses of halide-bridged [Ru(CO)2X(CH3C:C(H)C(H):N-iso-Pr)]2 and fac-Ru(CO)3X(CH3C:C(H)C(H):N-iso-Pr)

Wilhelmus P Mul,Jacques Spaans,Monique Van Leijen,Cornelis J Elsevier

doi:10.1021/om00047a057

Reactions of monoazadienes with metal carbonyl complexes. XII. Reactions of the linear tetranuclear ruthenium complex Ru4(CO)10(CH3C:C(H)C(H):N-iso-Pr)2 with oxidizing reagents. Syntheses of halide-bridged [Ru(CO)2X(CH3C:C(H)C(H):N-iso-Pr)]2 and fac-Ru(CO)3X(CH3C:C(H)C(H):N-iso-Pr)

Wilhelmus P Mul, Jacques Spaans + Show 2 more

https://doi.org/10.1021/om00047a057

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Journal: Organometallics	Publication Date: Jan 1, 1991
Citations: 9

#Organoruthenium Complexes #Elevated Temperatures + Show 4 more

Abstract
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Abstract

The linear tetranuclear complex Ru 4 (CO) 10 (CH 3 C=C(H)C(H)=N-i-Pr) 2 (1), containing two η 5 -azaruthenacyclopentadienyl systems, reacts with oxidizing reagents (I 2 , Br 2 , NBS, CCl 4 ) at elevated temperatures (40-90°C) in heptane or benzene to give the new dimeric halide-bridged organoruthenium (II) complexes

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