Abstract
The two diameters of the linear tetranuclear cluster Ru 4 (CO) 10 [CH 3 C=C(H)C(H)=N-i-Pr] 2 , (CA,/AC)-(1a) and (CC/AA)-1a, have been separated by preparative HPLC. Two different modes for diastereometer interconversion have been assessed; a thermally induced isomerization which proceeds intermolecularly, and a CO induced isomerization which occurs intramolecularly, as could be shown employing labeling experiments.
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