Abstract
AbstractThe electrochemical discharge at mercury electrodes of nickel and other metal ions dissolved in fused alkali metal salts has been studied by measuring the alternating current impedance of the electrodes. For nickel ion specific rate constants have been calculated and the effect on the rate constant of adding water, potassium chloride and bromide to the fused salt has been examined. The transfer coefficient for the nickel ion discharge reaction has been measured using a special stationary mercury drop electrode.
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More From: Zeitschrift für Elektrochemie, Berichte der Bunsengesellschaft für physikalische Chemie
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