Abstract
1. The C-alkylation reactions of indole with fluorobenzoyl, benzenesulfonyl, trifluoroacetyl, and unsubstituted hexafluoroisopropylimines were studied. The reactions proceed without a catalyst. The regioselectivity for the C3 indole atom was shown. 2. It was established that C-alkylation reaction of indole with imines containing fluorine is facilitated with increase in -I and -E effects of the substituent at the N atom of the imine.
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More From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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