Abstract
1. Treatment of 1,1,3,3,3-pentafluoropropene and of hexafluoropropene with aluminum chloride in CH3COCl or CHCl3 solution in the cold effects smooth replacement of fluorine by chlorine atoms with formation of CCl3--CH=CCl2 and CCl3-CF=CCl2, respectively. 2. The ready replacement of fluorine by chlorine atoms in these compounds is the result of the conjugation of bonds, which leads to mobility of fluorine atoms in the CF3 group and to ready allyl rearrangement.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
