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Abstract
AbstractThe reactions of enamines (1a–b, 4, 6) with fluorinated acyl chlorides (2a–d ) produced fluorinated 1,3‐diketones (3a–f) and 1,3‐keto‐aldehydes (7a–c) in good yields as well as byproducts fluorinated acylamides (5a–c). It is proposed that the reactions involve nucleophilic attack by the C‐atom and/or N‐atom of the enamines on acyl carbon of the fluorinated acyl chlorides.
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