Abstract
Abstract Carbon dioxide reacts with RuH2(PPh3)4 to give its insertion product, hydridoformatotris(triphenylphosphine)ruthenium(II). The reversibility of the CO2 insertion has been demonstrated. Insertion products of carbon disulfide and adducts of sulfur dioxide with ruthenium also have been obtained by the reactions of carbon disulfide and sulfur dioxide with various ruthenium dihydride complexes, RuH2L4 (L=PPh3, PPh2H, PPh2Me, PPhMe2). These compounds were characterized by IR and NMR spectroscopy, elemental analysis and chemical reactions.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
