Abstract
Abstract Dichlorobis (cyclopentadienyl) titanium(IV), Cp2TiCl2, reacts with bidentate Schiff bases such as salicylidene-4-anisidine, salicylidene-4-phenetidine, salicylidene-4-bromoaniline, salicylidene-4-iodoaniline and salicylidene-4-nitroaniline in a 1:1 molar ratio in refluxing tetrahydrofuran in the presence of trimethylamine, to yield Cp2Ti (SB)Cl, where (SB)− is the anion of the corresponding Schiff base, SBH. The derivatives have been characterised on the basis of their elemental analyses, molecular weights, conductance and spectral (IR, 1H NMR and electronic) characteristics.
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