Abstract

AbstractThe 1,3‐dipolar cycloadditions of 2,3,4,5‐tetrahydropyridine 1‐oxide (1) and 3,4‐dihydro‐2H‐pyrrole 1‐oxide (2) to methyl (E)‐6‐(benzyloxy)‐4‐hydroxy‐2‐hexenoate (3) and methyl (S)‐(E)‐3‐(2,2‐dimethyl‐1,3‐dioxolan‐4‐yl)propenoate (4) yield predominantly the adducts derived from endo transition states with antifacial approaches.

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