Abstract

The reactions of cobalt(III) acetylacetonate and cobalt(II) acetylacetonate with trimethylaluminium in the presence of 2,2′-dipyridyl (dipy) as an electron donor was studied. A mixture of methylcobalt complexes at a molar ratio dipy/Co of 2/1 was found to be formed from these reactions. Aluminium(III) acetylacetonate or aluminium dimethylacetylacetonate, depending on the molar ratio of reactants, are the other reaction products.

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