Abstract
The reaction of cationic complex [( 5-C 5Me 5)Re(CO) 3I] + with aliphatic and aromatic primary amines unexpectedly produced the chelated carbamoyl species trans-( 5: 1-C 5Me 4CH 2NRC( O))Re(CO) 2(I) ( 1, R = Me; 2, R = Pr; 3, R = Ph; 4, R = p-tolyl). The 1-coordination of carbamoyl moiety linkages to a methylene group of tetramethylcyclopentadienyl ligand was confirmed by X-ray crystallography of complex 3. All the complexes were isolated as pure samples and fully characterized by IR, 1H and 13C NMR spectroscopies, mass spectrometry and elemental analysis.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
