Abstract
The borole 2, obtained by 1,1-carboboration of phenylbis(trimethylsilylethynyl)borane with B(C6F5)3, undergoes [4 + 2] cycloaddition reactions with 1-pentyne and with ethene to give the 7-borabicyclo[2.2.1]heptadiene and -heptene derivatives, respectively. The borole 2 reacts with pyridine at room temperature to give a pyridine-stabilized borolium ion. The reaction proceeds by phenyl migration and Me3SiF elimination. Carbon monoxide reacts rapidly with the borole 2 at room temperature to give the unusual ketene derivative 19 with Me3Si migration across the ring system.
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