Abstract
Alkynes are important in organic synthesis. This review mainly focuses on recent advances (2013-2023) on alkynes with C-S bond formation, based on more than 30 types of sulfur reagents. The reactions of alkynes with various sulfur-containing compounds including RSSR (disulfides), RSH (thiols), S8 (elemental sulphur), alkynyl thioethers, RSCN, AgSCF3, K2S, Na2S, dithiane, RSCl, NFSI, RNCS, EtOCS2K, thiocarbamate, RSONH2, thiourea, sulfoxide, RSO2N3, CS2, RSO2NH2, RSO2NHNH2, RSO2Cl, RSO2Oar, RSO2SR', DABCO·(SO2)2, Na2S2O5, K2S2O5, RSO2H, RSO2Na and related compounds are discussed. Diverse mechanisms such as radical, electrophilic/nucleophilic addition, rearrangement, C-C bond cleavage, and CuAAC are discussed. The content is organized by substrates and reactivity patterns. We hope it will help in future research in this area.
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