Abstract
1. The authors have obtained 1∶1 adducts by the addition of acetic anhydride, malonic ester, propionic acid, and methyl monochloroacetate to 1-alkenes in the presence of tert-butyl hydroperoxide. 2. Initiation of addition is due mainly to the free radicals formed by thermal decomposition of tert-butyl peresters and tert-butyl hydroperoxide. 3. tert-Butyl peresters are formed by acylation of tert-butyl hydroperoxide by carboxylic acids, their esters, and anhydrides.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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