Abstract
The interaction of the ethyl ester or pyrrolidide of 3,3-diaminoacrylic acid with aromatic and heteroaromatic nitriles containing a labile halogen atom in the ortho position, leads to the formation of products of its substitution by the α-carbon atom of the diaminoacrylic acid derivative. The compounds obtained are cyclized smoothly into fused diaminoazines. Authors: E. M. Igumnova, S. I. Selivanov, D. V. Dar'in, and P. S. Lobanov. English Translation in Chemistry of Heterocyclic Compounds , 2012, 48 (3), pp 436-441 http://link.springer.com/article/10.1007/s10593-012-1011-5
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