Abstract
The thermally promoted reactions of some phenyl and diterpenoid η 2-(2-acylaryl-C,O)tetracarbonylmanganese (I) complexes with phenyl vinyl sulfone, methyl vinyl sulfone, or phenyl vinyl sulfoxide, have been investigated. The major products from the diterpenoid complexes arise from insertion followed by reductive demetallation; cyclopenta-annulation, when it occurs, is a minor process. Liberation of the metal-free adducts from their Mn-containing precursors requires treatment with either acid or photolysis-oxidation.
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