Abstract
δ-Functionalized α-nitrodienes are polyconjugated electron-deficient systems capable of vigorously reacting with nucleophilic reagents. The results of reactions of 1,4-dinitrodienes with aromatic amines and thiols are determined by nucleophilic attack at the middle or terminal carbon atom of the diene system [1, 2]. In the present communication we report the results of our study on reactions of 1-nitro-4-arylsulfonyldienes I and II with aromatic amines and of 1,4-dinitroand 1-nitro-4-sulfanyldienes III–V with N,S-binucleophiles. Products of addition of 2 equiv of aniline and ethanethiol to 1,4-dintrodienes [1, 2], as well as products of substitution by aromatic thiols, were reported previously.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
