Reaction zone structure and detonation parameters of nitromethane/polymethylmethacrylate and its mixture with microballoons

Abstract

In the present work, the detonation wave structure and detonation parameters for nitromethane (NM) and its mixtures with polymethylmethacrylate (PMMA) and glass microballoons (GMB) were studied by a velocity interferometer system for any reflector laser interferometer. The PMMA concentration varied from 2% to 4%. It is shown that PMMA additives lead to a change in the reaction zone structure, which can be observed as an appearance of a cellular instability of the detonation front. The detonation parameters of the mixture up to 3% PMMA are close to those of pure nitromethane and reduced when 4% PMMA is added. The addition of 2% GMB to the NM/PMMA mixture leads to the formation of a detonation front with a characteristic size of heterogeneities on the order of GMB diameter. In this case, the detonation parameters are reduced, and the values of the detonation velocity decrease by about 10% compared to NM/PMMA mixtures.