Reaction sintering of shock-compressed Ti + C powder mixtures

Abstract

Shock compression was used to make dense compacts of Ti and C elemental powder mixtures for subsequent reaction sintering in near-net form. The reaction sintering experiments were performed in an induction-heated hot press at temperatures below the melting point of Ti, with hold times of less than a few hours. The unique combination of defect states and packing characteristics introduced during shock compression results in significant enhancement in the solid-state chemical reactivity of the powder mixtures. Consequently, the reaction behavior of the powders is altered, and the reaction mechanism is dominated by solid-state diffusion, resulting in a microstructure reminiscent of solid-state processes. Reaction-sintered TiCx compacts, with bulk density in the range of 3.9 to 4.2 g/cm3 (80 to 85 pct TMD of TiC), were produced in near-net form. The compacts had a highly refined microstructure (<6-μm grain size) and microhardness in the range of 1360 to 1934 KHN. In this article, reaction sintering mechanisms involving solid-state diffusion in Ti + C powder mixture compacts will be described, along with characteristics of the titanium carbide produced by the com-bined shock modification and reaction sintering approach.