Abstract
1. The reactions of α-hydroxymethylmalonic and bis-(α-hydroxymethyl)malonic esters with triethyl phosphite, trimethyl phosphite, and diethyl chlorophosphite have been studied. 2. Diethyl 2,2-dicarbethoxyethylphosphonate was obtained from the reactions ofα-hydroxymethylmalonic ester with triethylphosphite and diethyl chlorophosphite. 3. 2-Alkoxy-2-oxo-4,4-dicarbethoxy-1-oxa-2-phospholans were isolated from the reaction of bis-(α-hydroxymethyl) malonic ester with trialkyl phosphites and with diethyl chlorophosphite.
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