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Abstract
1. The telomerization of vinyl chloride (VC) with bromoform, with initiation by coordination initiators based on Fe(CO)5, proceeds with a greater conversion of the telogen and an increased yield of lower telomers when compared with initiation by benzoyl peroxide. Together with the CHBr2 (CH2CHCl)nBr (n=1−3) telomers, a small amount of 1,3-dibromo-1,3-dichloropropane is formed. 2. Under the reaction conditions, the CHBr2CH2CHClBr telomer is capable of reacting with VC, with cleavage of the C-Br bonds of both the CHBr2 and CHClBr groups. 3. We were able to add 1,1,3-tribromopropane and 1,3-dibromo-1-chloropropane to VC by initiation with Fe(CO)5 + DMF.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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