Abstract
AbstractNickel perchlorate catalyzed sequential Meinwald rearrangement of a terminal oxirane through C–O bond cleavage, and cycloaddition with a donor–acceptor oxirane through C–C bond cleavage was developed. The same catalyst mediates the ring opening of the oxirane moiety in two different ways. This method provides an alternative route to synthesize highly substituted 1,3‐dioxolanes by using oxiranes instead of aldehydes.
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