Abstract

Abstract The reaction of tris(trimethylsilyl) phosphite with halohydrins does not lead to an Arbuzov product but to bis(trimethylsilyl) esters of 3-halo-2-trimethylsiloxypropylphosphonic acids. Methanolysis and neutralization affords the 3-halo-2-hydroxypropylphosphonic acids and their salts.

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