Abstract
1. The reaction between trimethylsilylmethylmagnesium chloride and the ethyl esters of acetic and n-butyric acids proceeds normally, in the direction of the formation of tertiary alcohols, but is accompanied by 3 -decomposition, the splitting off from these alcohols in acid medium of one trimethylsilyl group. 2. When tertiary organosilicon alcohols containing a hydroxyl group on the β-carbon atom are dehydrated, unsaturated silicohydrocarbons are formed with a double bond in the β-position.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
