Abstract
In the reaction of CCl3CH3 with CCl2=CHCH2CH2CH2Cl, and of CCl3CH2CH2Cl with CCl2= CHCH2Cl, initiated by Fe(CO)5+DMF, the main addition products are respectively compounds of structure HCCl2CH(CCl2CH3)CH2CH2CHCl2 and HCCl2CH(CCl2CH2CHCl2)CH2C1. The formation of these compounds was explained by the isomeriza'tion of the radical-adducts CCl2CH(CCl2CH3)CH2CH2CH2Cl and CCl2CH(CCl2CH2CH2Cl)CH2Cl, with migration of a hydrogen atom from the CH2Cl groups found in the 5 position to the radical center.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
