Abstract
Sugar oxazolines, obtained by a dehydration reaction of 2-acetylamino pyranosides, reacted with primary amines in water to produce sugar imidazolines, which, when heated in water, were converted to sugar imidazoles by a dehydration reaction. The structures of these rather unexpected reaction products were determined by spectroscopic data. This offers a simple process to introduce a glycan onto peptides, proteins, and other biologically important compounds.
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