Reaction of Re(2)(mu-O(2)CCH(3))(4)Cl(2) with Bis(dicyclohexylphosphino)methane (dcpm): isolation of the mixed-valent complex O(3)ReReCl(eta(2)-dcpm)(2) containing an unsupported Re-Re bond.

Jitendra K Bera,Phillip E Fanwick,Richard A Walton

doi:10.1021/ic0100471

Reaction of Re(2)(mu-O(2)CCH(3))(4)Cl(2) with Bis(dicyclohexylphosphino)methane (dcpm): isolation of the mixed-valent complex O(3)ReReCl(eta(2)-dcpm)(2) containing an unsupported Re-Re bond.

Jitendra K Bera, Phillip E Fanwick + Show 1 more

https://doi.org/10.1021/ic0100471

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Journal: Inorganic chemistry	Publication Date: May 2, 2001
Citations: 16

Affiliation: Purdue University West Lafayette

#Reaction Of Re2 #Separable Mixture

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Abstract

The reaction of Re2(μ-O2CCH3)4Cl2 with Cy2PCH2PCy2 (dcpm) affords a separable mixture of trans-ReOCl(η2-dcpm)2 (1) and trans-Re2(μ-O2CCH3)2Cl2(μ-dcpm)2 (2). Complex 1 is converted in the presence of O2 to the novel mixed-valent Re(VI)−Re(I) complex O3ReReCl(η2-dcpm)2 (3), which contains an unsupported Re−Re bond.

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