Abstract
Pulse radiolysis studies are reported on reactions of radicals of different electronic structure (chloroalkyl-, α-, β-hydroxyalkyl-) with benzoquinone and its methyl-substituted derivatives in non-polar surroundings. Hence, radical addition onto the quinones resulted in substituted semiquinone radicals, whereas electron transfer reduction generated semiquinone radical anions, which could be clearly identified in cyclohexane solution.
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