Abstract

1. In presence of di-t-butyl peroxide as initiator, piperidine reacts withα-olefins of iso structure (2-methylpropene, 3-methyl-1-butene) with formation of a C-alkylpiperidine. The isopentylpiperidine obtained has not been described previously. 2. Tetrahydropyridine and its dimer are also formed in the process.

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