Abstract
Abstract Our present work is a continuation of the investigations devoted to the synthesis of sugar thiiranes.1 We found that careful monitoring of the reaction of monothio acids of phosphorus with 5,6-anhydro-1,2-O-isopropylidene-α-D-glucofuranose 1 allows deeper insights into the mechanism of that reaction. It affords new, convincing arguments for the participation of the pentacoordinate intermediate 8 in the transphosphorylation step 3 → 4.
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