Abstract
Interaction of palladium bis(acetylacetonate) with diphenylphosphine is studied by NMR, IR, and UV methods. Reaction between reagents taken in equimolar amounts gives binuclear and trinuclear palladium complexes with bridging diphenylphosphide and the chelate acetylacetonate [Pd(Acac)PPh2]2 and [Pd3(Acac)2(PPh2)4] ligands. With excess PPh2H, the trinuclear palladium complex, whose composition is supposed to be [Pd3(PPh2)4(PPh2–PPh2) · C6H6], is isolated and characterized on the basis of the spectral data.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
