Abstract
The rate coefficient for the reaction O(3P) with ClONO2, k1, was measured between 202 and 325 K using two methods: pulsed laser photolysis with time-resolved atomic resonance fluorescence detection of the O atoms and pulsed laser photolysis with long-path tunable diode laser absorption for detection of NO3 radicals. The measured rate coefficient is summarized by k1 = (4.5 ± 1.4) × 10-12 exp[(−900 ± 80)/T] cm3 molecule-1 s-1, with k1(298 K) = (2.2 ± 0.2) × 10-13 cm3 molecule-1 s-1. The yield of NO3 radical in this reaction was measured to be essentially unity. Our results are compared with those from previous studies.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
