Abstract
The reaction of methylmagnesium iodide with di(n-butyl)cyanamide results in dibutylamine, dibutylisopropylamine, and acetonitrile, while the reaction with di(n-butyl)nitrosamine affords acetaldehyde dibutylhydrazone. Formaldehyde, acetone, and 2-butanone dibutylhydrazones, as well as acetaldehyde butyl(1-methylbutyl)hydrazone, 2-butanone butyl(1-methylbutyl)hydrazone, 1,1-dibutyl-2,2-dimethylhydrazine, and 1,1-dibutyl-2-ethyl-2-methylhydrazine were also identified in minor amounts. Di(n-butyl)nitramine reacts with methylmagnesium iodide to give di(n-butyl)nitrosamine.
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