Abstract

1. Methyl esters of fluoroalkyl-ontainingα-keto acids form addition products with acetamide at theα-keto group of the ester. 2. Methyl esters of fluorine-containingα-keto acids react with hydrazine hydrate and ethylenediamine to give addition products at theα-keto group, and at the same time the aminolysis products of the carbomethoxyl group. Products of this type, formed from esters with a perfluorobutyl group, undergo haloformic decomposition. 3. Methyl esters of fluoroalkyl-containingα-keto acids react with o-phenylenediamine to form 2-hydroxy-3-fluoroalkylquinoxalines.

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