Abstract
Abstract Interaction of (indol-3-yl)ethane-1,2-diol with L-ascorbic acid under mild conditions yielded a mixture of products of the L-ascorbic acid 2-C alkylation with the substituted skatyl cation stabilized by the 3-CO hemiketal formation with the participation of the HOCH 2 moiety of (indol-3-yl)ethane-1,2-diol. Under the action of ethanolic HCl, tricyclic ketals were formed. The stereochemical configuration of the compounds was determined by NMR methods.
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