Reaction of gold(III) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6]. Crystal structure of [Au(bipy(ip))(eta2-CH2=CHPh)][PF6] (bipy(ip) = 6-isopropyl-2,2'-bipyridine).

Maria A Cinellu,Sergio Stoccoro,Giovanni Minghetti,Mario Manassero,Antonio Zucca

doi:10.1039/b404890c

Reaction of gold(III) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6]. Crystal structure of [Au(bipy(ip))(eta2-CH2=CHPh)][PF6] (bipy(ip) = 6-isopropyl-2,2'-bipyridine).

Maria A Cinellu, Sergio Stoccoro + Show 3 more

https://doi.org/10.1039/b404890c

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Journal: Chemical communications (Cambridge, England)	Publication Date: Jan 1, 2004
Citations: 64

Affiliation: University of Sassari, University of Milan

#Oxo Complexes #Structure Of Adduct + Show 4 more

Abstract
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Abstract

Gold alkene complexes [Au(bipyR)(eta2-alkene)][PF6] (bipyR = 6-alkyl-2,2'-bipyridine) have been obtained by reaction of gold(III) oxo complexes [Au2(bipyR)2(mu-O)2][PF6]2 with alkenes. The crystal structure of the styrene adduct [Au(bipy(ip))(eta2-CH2=CHPh)][PF6] (bipy(ip) = 6-isopropyl-2,2'-bipyridine) has been solved by X-ray analysis.

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