Abstract

Vibrationally excited CO ( v), HCO ( ν 1, ν 2), HNC ( ν 3) and HCN ( ν 3) were observed as products of the reaction of C 2H with NO by using time-resolved FTIR emission spectroscopy. Three exothermic reaction channels leading to HCN+CO, HNC+CO and CN+HCO are identified, verifying an association-elimination reaction mechanism. The nascent products of CO ( v⩽10) and CO 2 ( ν 3, v⩽3) were observed for the reaction of C 2H with O 2. A yield ratio of CO/CO 2 is estimated as 9. The experimental observations suggest that reaction is rapid and forms CO and HCO.

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