Abstract
n-Butyl orthotitanate (BT) reacts with a stoichiometric amount of benzoyl peroxide (BP) to form complexes of composition [3BT·BP] and [BT·BP]. The fastest decomposition of BP proceeds via the [3BT-BP] complex, i. e., with an excess of BT relative to BP. Butoxyl radicals are formed during the decomposition of the complexes. The end product when BP is decomposed by BT is di-n-butoxytitanium dibenzoate, which does not accelerate the decomposition of BP.
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