Abstract

1. Nitroacetic ester reacts with open-chain ketals of aliphatic and alicyclic ketones in Ac2O medium with formation of esters of the correspondingβ-alkoxy-α-nitrocarboxylic acids. 2. A series ofβ,β-disubstituted α,β-dehydro-α-acetylamino acid esters was prepared by catalytic reduction of the compounds obtained and subsequent acylation and cleavage of alcohol.

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