Abstract

A phenylsulfonyl group in the 3 position accelerates and changes the direction of aminolysis of benzothiazolone and leads to the formation of 2-phenylsulfonylamino-S-phenyl esters of N-substituted thiocarbamic acids. 2,2′-Bis(phenylsulfonylamino)diphenyl disulfide and the corresponding symmetrical ureas were obtained in the reaction with several primary amines.

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