Abstract

Reaction of 2-methoxy-N-(1-methylpropylidene)-1-(methylsulfanyl)buta-1,3-dien-1-amine with ButOK resulted in 2-ethylidene-6-methoxy-7-(methylsulfanyl)-3,4,5,6-tetrahy-dro-2H-azepine, the first example of 2-ethylidene-3,4,5,6-tetrahydro-2H-azepines, along with hitherto unknown 7-ethyl-3-methoxy-2-(methylsulfanyl)-4,5-dihydro-3H-azepine and 2-ethyl-6-methoxy-3H-azepine.

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