Abstract
In many industrial applications, (CF3)2CFCN has been suggested as SF6 substitute, which possess a global warming potential (GWP100-yr) of 23500 relative to CO2. The temperature dependence of the rate coefficient (kOH) for the OH+(CF3)2CFCN reaction is reported for the first time: kOH(278–358K)=(5.9±3.2)×10−13exp{−(1856±162)/T}cm3 molecule−1s−1. A lifetime of 47years was estimated relative to that of CH3CCl3. Infrared absorption cross sections were also determined to derive the radiative efficiency (0.28Wm−2ppbv−1). A GWP100-yr of 3646 was estimated, resulting in a significant reduction of the contribution to global warming if SF6 was replaced by (CF3)2CFCN.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callSimilar Papers
More From: Chemical Physics Letters
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
