Abstract
Resonance fluorescence has been used to determine the rate constants k1 and k2(cm3 molecule–1 s–1)(1 σ) of elementary reactions of ground state OH X2Π radicals from 293 to 430 K: OH + CH3CCl3[graphic omitted]CH2CCl3+ H2O (1), log10k1=(–11.62 ± 0.14)–(1394 ± 113)/2.303 T; OH + CO [graphic omitted] CO2+ H (2), k2=(–12.66 ± 0.12)–(88 ± 40)/2.303 T.
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