Abstract

Abstract The Ca ( 1 D 2 , 3 P J ) + RI ( R  CH 3 , C 2 H 5 , n - C 3 H 7) → CaI ( A,B ) + R reaction system has been studied by measuring its chemiluminescence under beam gas conditions. Absolute values of the reaction cross-sections were determined at low collision energy E T ≤ 0.20 eV . In addition, the electronic branching ratio, photon yield and influence of the radical size group on the reaction cross-section have been estimated. The results are discussed in the light of different reaction mechanisms involving the attacking Ca atom into the Cz.sbnd;I bond.

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