Abstract

In cyclohexane and under UV radiation, 3,4-dimethylphosphacymantrene ((C 6H 8P)Mn(CO 3) yields the monosubstituted products (C 6H 8P)Mn(CO) 2L with various phosphines and trimethylphosphite (L). With trimethylphosphite also the disubstituted derivative is obtained.

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